Aniline CAS# 62-53-3

Aniline CAS# 62-53-3

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Chemical Name:Aniline
CAS No.:62-53-3
Molecular Formula:C6H7N
Molecular weight:93.13
Sample: Available
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Product Description

Aniline CAS# 62-53-3

Aniline is the easiest important fragrant amine and a compound shaped via the substitution of a hydrogen atom in the benzene molecule with an amino group. It is colorless oil like flammable liquid with robust odor. When heated to 370 C, it is barely soluble in water and soluble in ethanol, ether, chloroform and different natural solvents. It will become brown in the air or below the sun. It can be distilled by way of steam. A small quantity of zinc powder is brought to stop oxidation when it is distilled. The purified aniline can be brought 10 ~ 15ppm NaBH4 to stop oxidation deterioration. The answer of aniline is alkaline.
It is convenient to produce salt when it reacts with acid. The hydrogen atoms on its amino organizations can be substituted with the aid of alkyl or acyl corporations to produce 2nd or 1/3 grade aniline and acyl aniline. When substitution response occurs, the merchandise of ortho and para substituted merchandise are primarily produced. It reacts with nitrite to structure diazonium salts, which can be used to produce a sequence of benzene derivatives and azo compounds.

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Aniline Chemical Properties


Melting point

-6 °C (lit.)

Boiling point

184 °C (lit.)

density

1.022 g/mL at 25 °C (lit.)

vapor density

3.22 (185 °C, vs air)

vapor pressure

0.7 mm Hg ( 25 °C)

refractive index

n20/D 1.586(lit.)

Fp

76 °C

storage temp.

2-8°C

solubility

water: soluble

form

Liquid

pka

4.63(at 25℃)

color

APHA: ≤250

Specific Gravity

1.021

Odor

Sweet, amine-like odor detectable at 0.6 to 10 ppm

Relative polarity

0.42

PH

8.8 (36g/l, H2O, 20℃)

PH Range

8.1

explosive limit

1.2-11%(V)

Water Solubility

36 g/L (20 ºC)

Merck

14,659

BRN

605631

Henry's Law Constant

1.91 at 25 °C (thermodynamic method-GC/UV spectrophotometry, Altschuh et al., 1999)

Exposure limits

TLV-TWA skin 2 ppm (~8 mg/m3) (ACGIH), 5 ppm (~19 mg/m3) (MSHA, OSHA, and NIOSH); IDLH 100 ppm (NIOSH).

Dielectric constant

7.8(0℃)

Stability:

Stable. Incompatible with oxidizing agents, bases, acids, iron and iron salts, zinc, aluminium. Light sensitive. Combustible.

LogP

0.900

CAS DataBase Reference

62-53-3(CAS DataBase Reference)

IARC

2A (Vol. 27, Sup 7, 127)

NIST Chemistry Reference

Aniline(62-53-3)

EPA Substance Registry System

Aniline (62-53-3)


Safety Information


Hazard Codes

T,N,F

Risk Statements

23/24/25-40-41-43-48/23/24/25-50-68-48/20/21/22-39/23/24/25-11

Safety Statements

26-27-36/37/39-45-46-61-63-36/37-16

RIDADR

UN 1547 6.1/PG 2

OEL

TWA: None ppm

WGK Germany

2

RTECS

BW6650000

F

8-9

Autoignition Temperature

615 °C

TSCA

Yes

HS Code

2921 41 00

HazardClass

6.1

PackingGroup

II

Hazardous Substances Data

62-53-3(Hazardous Substances Data)

Toxicity

LD50 orally in rats: 0.44 g/kg (Jacobson)

IDLA

100 ppm


Product Usage

Aniline is an necessary industrial chemical for many decades. Currently, it is most extensively used for the manufacture of polyurethanes and rubber, with lesser quantities ate up in the manufacturing of pesticides (herbicides, fungicides, insecticides, animal repellants), defoliants, dyes, antioxidants, antidegradants, and vulcanization accelerators. It is additionally an ingredient of some family products, such as polishes (stove and shoe), paints, varnishes, and marking inks.

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